Heat
The third point of the triangle is heat. Fuel and oxygen without heat, will not ignite. The fuel needs heat at a specific temperature – its ignition temperature – before it will burn. For the fire to continue burning, it needs to maintain that heat. If the fuel can be cooled down enough, the fire will be extinguished. For example, pouring water onto a wood fire cools the wood.
When fuel is heated, it gives off vapours and it is these vapours that burn. This rapid oxidation produces heat and light (flames). The fuel could be a solid (e.g. wood) or a liquid (e.g. petrol). Remove one of these elements in the fire triangle, and the fire will go out.
The temperature at which material will burn fall into three categories:
Flash point
The lowest temperature, at which a substance gives of sufficient flammable vapour to produce a momentary flash on the application of a small flame.
Fire point
The lowest temperature at which heat generated by combustion of the flammable vapour is capable of producing sufficient vapour to enable combustion to continue.
The difference between Flash point and Fire point is that Flash point temperature is only required to produce vapour to enable a momentary flash to take place, whereas Fire point temperature has to be high enough to produce sufficient vapour to maintain combustion.
Spontaneous Ignition
The lowest temperature at which the spontaneous ignition of a substance can take place. Carbon is the principal ingredient of all organic matter and has the characteristic of wanting to chemically combine with the oxygen in air. The surrounding air absorbs the heat generated by this reaction. (Atmosphere).
Tight compaction and confined spaces however cause the temperature to rise, which in turn accelerates the chemical reaction, until a temperature is reached where the substance bursts into flames. The temperature is called the IGNITION TEMPERATURE. This is not a fixed temperature and varies a lot due to factors such as surrounding temperatures etc.
Oily rags in a lubrication pit may readily absorb oxygen and generate enough heat to reach ignition.
The uncontrolled mixing (or accidental contact) of acids and oils could generate rapid temperature increases readily reaching the ignition temperature.
A compost heap may undergo oxidation under influence of microorganisms. If the generated heat is not dissipated rapidly enough, the ignition temperature may be reached.
Ignition Sources
We now see that a fire is not necessarily started by an open flame or spark but by heat.
The main sources of ignition are the following:
Electrical
21 % caused by poorly maintained electrical appliances (especially motors), overloaded circuits, and abuse of appliances, using the wrong or poorly maintained appliances in hazardous areas and to a lesser extent, static sparks.
Friction
14 % caused by hot bearings, miss-aligned or broken machine parts, choking or jamming of materials and poor adjustments of power drives and conveyors.
Foreign substances
12 % caused by particles of metal or stone mixed with materials being processed causing machine sparks.
Open flames
9 % caused by mainly the abuse and misuse of cutting and welding torches, gas and oil burners and petrol / paraffin torches.
Smoking and matches
8 % caused by smoking where combustible materials are present.
Spontaneous ignition
8 % caused by oily waste and rubbish deposits in dryers, ducks, fuels and low-grade material wastes in storage and materials exposed to some form of heating.
Hot surfaces
7 % caused by materials exposed to heat of boilers and furnaces, hot ducts, pipes and fuels, electrical irons and lamps and hot metal being processed.
Combustion sparks
6 % caused by sparks released from rubbish burning, furnaces, fireboxes, process equipment and industrial trucks and tractors.
Overheated material
3 % caused by normal process temperature especially those involving heated flammable liquids and substances in dryers.
Other
12 % caused by other less common or unknown causes.